(2,2′-Bipyridine-κ2 N,N′)bis(4-methylbenzoato-κ2 O,O′)zinc(II)
نویسنده
چکیده
In the title compound, [Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by four O atoms from two chelating 4-methyl-benzoate ligands and two N atoms from a 2,2'-bipyridine ligand, displaying a disordered octahedral geometry. C-H⋯O hydrogen bonds connect the complex mol-ecules into a three-dimensional supra-molecular structure.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′)bis(4-methylbenzoato-κ2 O,O′)lead(II)
In the title compound, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Pb(II) ion is coordinated by two N atoms from one 2,2'-bipyridine ligand and four O atoms from two 4-methyl-benzoate anions in a distorted pseudo-square-pyramidal environment, considering one of the carboxyl-ate anions as an apical ligand. Pairs of complex mol-ecules related by inversion centers are organized into dimers via pairs...
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In the dimeric title compound, [Zn(2)(C(14)H(9)O(4))(4)(C(10)H(8)N(2))(2)], the Zn(II) ions are penta-coordinated by one 2,2'-bipyridyl ligand and by three O atoms from three 2'-carboxyl-atobiphenyl-2-carboxylic acid ligands. Two of the 2'-carboxyl-atobiphenyl-2-carboxylic acid ligands act as bridging ligands and, together with two zinc(II) cations, produce an 18-membered ring system. The remai...
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The crystal structure of the title compound, [Zn(2)(C(8)H(7)O(2))(4)(H(2)O)(2)]·[Zn(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)]·2H(2)O, consists of two kinds of dinuclear Zn(II) complexes (complex A and complex B) and uncoordinated water mol-ecules. In complex A, [Zn(2)(C(8)H(7)O(2))(4)(H(2)O)(2)], each Zn cation is chelated by a 4-methyl-benzoate (PMB) anion and coordinated by a water mol-ecule, an...
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The reaction of lead acetate, 4-hydroxy-benzoic acid and 2,2'-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy-benzoate ligands, one 2,2'-bipyridine ligand and one uncoordinated water mol-ecule. The Pb(II) atom is hexa-coordinated in a distorted tetra-gonal-bipyramidal geometry and is c...
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In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two bridging 2,2'-oxydibenzoate ligands. The mol-ecule is a centrosymmetric dimer. π-π Stacking inter-actions are observed between the 4,4'-dimethyl-2,2'-bipy...
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